| SL.NO | FULL NAME | YEARS |
| 1 | Bishop Charles Lavigne SJ | 1887-1896 |
| 2 | Bishop Mathew Makkil | 1896-1911 |
| 3 | Bishop Thomas Kurialacherry | 1911-1925 |
| 4 | Bishop James Kalacherry | 1927-1949 |
| 5 | Archbishop Mathew Kavukatt | 1950-1969 |
| 6 | Archbishop Antony Padiyara | 1970-1985 |
| 7 | Archbishop Joseph Powathil | 1986-2007 |
| 8 | Archbishop Joseph Perumthottam | 2007-2024 |